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2022-1-28 · Is alum powder poisonous? Aluminum sulfate is fairly non-toxic, with acute and chronic oral LD50 both greater than 5,000mg/kg (5). However, alum can still cause irritation, burns, and respiratory issues. If inhaled, it may cause headaches, nausea, and respiratory irritations. Alum is not listed as a carcinogen by NTP, IARC, or OSHA.